Articles

The purpose of this work was to study the absorption capacity of degraded soils of agricultural land (using the ex- ample of agricultural farms in the southern part of the Shakhtersky district of the Donetsk People’s Republic). The main objectives of the research included studying the amount of exchangeable bases, exchangeable calcium and exchangeable magnesium. To study the soil cover of agricultural lands, model sites of varying degrees of degradation were selected. When choosing them, factors such as the prevalence of the type of disturbance within the study site, the degree of anthropogenic transformation, and the type of cultivated crop were taken into account. Soil sampling was carried out in September 2023. It was found that the most significant decrease in the amount of exchangeable bases was recorded in areas left fallow after growing a number of crops — sunflower, corn and wheat. The values of the sum of exchangeable bases were reduced compared to the control by 56–85%. The indicators of exchangeable calcium in the soils of the studied agrocenoses varied fr om 5,5 to 38,08 mEq×100 g-1 of soil, which depended on the position of the site in the landscape, the link in the crop rotation system, and the type of crop being cultivated. The lack of a proper soil care system in the studied areas affected the content of exchangeable calcium, reducing its content by an average of 42,7–84,8%. The percentage of magnesium from the total exchangeable bases ranged from 14,3 to 20,6%. The most significant decrease in the content of exchangeable calcium and magnesium in relation to the control was recorded in sites after sunflower cultivation, as well as in areas left fallow, wh ere the combined effect of a number of unfavorable factors (sloping surface, predecessor crop with an increased level of removal of mineral nutrition elements) influenced the change this indicator.

Dry steppe chestnut soils (Kastanozems) of the Tamsagbulag oil field are subject to intensive technogenic impact of oil production facilities. It has been established that the technogenic impact on chestnut soil during oil production is manifested in the discreteness of physical-chemical parameters in the surface horizon. The value of the miner- alization of the aqueous extract ranged from 32.5 to 325.0 mg∙L-1, the specific electrical conductivity from 65.4 to
647.0 μS∙cm-1. The concentration of hydrocarbons (HC) varied from 7 to 647 mg∙kg-1 and, with rare exceptions, was at the level of background values (100 mg/kg) established for oil production areas. The proportion of HC from the organic carbon content Corg varied widely, from 0.01 to 6.20%. Gas-chromatographic analysis of the molecular weight distribution of n-alkanes in the composition of HC showed that high-molecular homologues C27–C39 dominate in the surface horizon of the soil, with a sufficiently high degree of transformation of individual odd n-alkanes. The proportion of average molecular weight homologues ∑C22–C25 did not exceed 8% of the sum of n-alkanes. In the microbial community, heterotrophic bacteria dominated among the ecological-trophic groups of microorganisms (unicellular bacteria, actinomycetes, micromycetes), in their composition the proportion of oil-oxidizing bacteria was 9.1–39.3%. The process of destruction of petroleum HC was accompanied by the formation of a wide range of volatile organic compounds. It is shown that the quantitative and qualitative composition of oil components in the surface horizon of soils is determined by two processes — vertical migration and transformation of hydrocarbons, which compensate for the accumulation of oil.

The article presents the results of measuring the toxicity of soils with a specific activity of 137Cs in the range of 3,3∙102–1,3∙106 Bq∙kg-1, the flux density of β-particles and the dose rate of γ radiation on the surface of a bulk sample of 5,4-192,7 imp∙sec-1∙cm-2 and 0,2-2,7 μSv∙h-1, respectively. The forms of toxicity were detected in a solid-phase biotest with Allium cepa L., simulating the situation of external irradiation of dividing cells in contact with soil. The toxic effect was assessed relative to the control as mitotoxicity by reducing the mitotic index and as genotoxicity by inducing chromosomal aberrations, taking into account the contribution of the clastogenic effect. The value of the mitotic index in a series of biotests with contaminated soil decreased to values of 8,6±1,1–14,6±2,3% compared with the control proliferation level of 14,9±1,2%. At the same time, the frequency of chromosomal aberrations increased conjugately from 4,7±0,3 to 18,2±3,3%, with a control level of 3,9±0,5%, with an increase to 68% of the proportion of pathologies associated with clastogenic effects on chromosomes. A number of significant correlations between the values of toxicity indexes and indicators of radioactive contamination of soils have been revealed.

Water erosion is one of the most extensive processes of soil and land degradation. This process significantly deteri- orates the quality of ecosystem services provided. Studying the mechanism and consequences of this phenomenon will help develop strategies to mitigate its impact on the environment. One of the challenges in studying water erosion is the high cost of conducting field research over large areas. Another challenge is the limitation of existing models, which are often developed for specific regions. Our research aims to address these problems by adapting the widely used RUSLE2 model to local conditions. Beijing was chosen as the study area due to its rich information resources and extensive results from field measurements of soil water erosion. Calculations were performed using a raster data model, which included a slope angle model, slope length, soil erodibility, rainfall erosion potential factors from precipitation and snowmelt, land use types, and vegetation cover management factors. All data were taken from open sources. The average soil erosion in the studied area was 25 t·ha–¹ per year. The discrepancy with other studies was less than 1%. The modified RUSLE2 model showed good results, correlating with other studies in this area.

Erosion-accumulation processes are realized through paragenetic processes of soil destruction, transport, redepo- sition and accumulation of pedosediments enriched in organic carbon. A promising approach in modern methods for substantiating permissible erosion losses of soils is the integration of assessments of the quality of soil resources, the rate of erosion and soil formation, including calculations of the balance of organic carbon in soils of agroeco- systems. The range of research tasks included: analysis of current integrated approaches to justify the permissible erosion losses of soils that are the most promising from the point of view of the completeness of reflection of ag- ropedogenesis; assessment of the effectiveness of the process of regeneration of the humus horizon under primary, recent and postagrogenic variants of soil reproduction; identification of patterns of formation of natural soil cover on dated and full Holocene erosional pedotopocatena; determination of the effectiveness of erosion-accumulation processes in the formation of pedosediments enriched with organic carbon in the thalwegs of runoff depressions during an extreme hydrological event and in accumulative elements of the landscape over a centuries-long period. The main objects of the study were soils of different ages in a state of renaturation, which were selected in anthropo- genically disturbed geosystems of the European forest-steppe. In addition, soil-geomorphological features within different-aged erosional pedotopocatenes and processes of accumulation of pedosediments at different scale levels were studied.
The results of mathematical modeling of the soil-forming process over time, based on an extensive database of soil-chronological data, show significant differences in the rate of formation of the humus horizon at the initial and quasi-final stages of pedogenesis, as well as the relationship between the ontogenetic maturity of the humus profile and the rate of pedogenesis, which must be taken into account when justifying acceptable erosion losses. Long-term studies of the processes of renaturation of disturbed soils in the forest-steppe zone have identified a special type of reproduction in Agroabrozems, when functional rehabilitation of the residual humus horizon occurs, which differs from primary pedogenesis during the formation of a humus profile on parent rocks. Depending on the erosional transformation of the predecessor soil profile, the average rates of formation of the postagrogenic humus horizon in forest-steppe Chernozems range from 3,6 to 6,0 mm·year–1. As shown by the results of studying different-age and full-Holocene pedotopocatenes, the natural soil cover, which reflects the processes of erosion-accumulation and landscape slope microzonality, and soil-geomorphological relationships can be adequately formalized by improving the formula for calculating the relief function in erosion models through the introduction of a variable power value for the slope length index.

In the paper spatial and temporal variability of soil erosion for the periods of 1958–1988 and 1989–2018 is estimated
on the basis of RUSLE in Crimea. Erosion rates vary from very slight to very high in the region. Strongly eroded
areas are found in the mountainous regions in the Southern Crimea, mainly attributable to a combination of a high
rainfall erosivity (R-factor) and relatively steep slopes (LS-factor). Soil loss in 1958–1988 exceeded the values in
1989–2018 on approximately 13%, while the share of moderate, high and very high-eroded areas varied within the
range of less than 1%. € ese changes are associated with both the reduction of agricultural cultivated lands and the
variability of soil erosion factors. € e soil erosion formation is mainly connected with the factors of rainfall erosivity,
slope steepness as well as the cover-management factor in Crimea. Comparison of actual suspended sediment yield
in the gauges with the values of soil erosion demonstrated that most rivers area characterized by the accumulation
of eroded material when 10–50% of the washed products reach the gauges.

The study of erodibility of model soils using the methodology of washing out soil samples with a water stream in a hydrodynamic tube has been carried out. In comparison to the traditional method of vertical loading of cartridges, the new method of soil samples formation using horizontal loading allowed to obtain more homogeneous resistance of samples in the process of their erosion by water flow, to which the formed layers of soil aggregates are located perpendicularly. The use of the «Poseidon» measuring device made it possible to obtain washout intensities in dynamics, to evaluate the quality of sample preparation and to analyze the data in order to cull them, especially in the beginning and the end of the experiments. In addition, the use of the device allowed to skip some operations needed to clarify the data of experiments at their early termination (remainder accounting that requires drying to determine the mass of washed out soil by difference). The data files generated by the device at the end of experiments significantly simplified their processing and considerably reduced the time required for it. The coefficient of varia- tion of the washout intensity value decreased by 12% on average when using the new method of sample preparation compared to the previous one. The moisture ranges with minimum erodibility have been established for model soils. Dependences of soil washing intensity on water flow velocity in the range from 0.5 to 2.5 m∙s–1 were demonstrated. The results confirm the correlation of soil washout intensity with the cube of the flow velocity. Soil erodibility was determined as a coefficient of proportionality between the intensity of soil washout and the cube of flow velocity. The maximum erodibility coefficient typical for agrogray soil equals to 179×10–6, and the minimum value obtained for agrochernozem was 53.0×10–6 s2∙m–2. Agrosod-podzol soil features the intermediate value of erodibility coefficient: 80.3×10–6 s2∙m–2. The proposed methodological approaches and obtained experimental results can be further used to assess the erodibility of soil and soil monoliths and model samples of polyfractional composition close to natural.

Land degradation is a global problem of humankind, where the greatest contribution belongs to aridity and soil erosion. The social consequences of land degradation are extremely important, but poorly conceptualized issues. This makes it difficult to create effective research programs to study them. The article provides an overview of the issues under consideration. An expert study was conducted to identify a problem field in the field of studying the social consequences of land degradation. By interviewing nine recognized scientific experts in the field of land degradation studies, the most stable judgments were identified, which served as a basis for highlighting the main forms of manifestation of the social consequences of land degradation. Private research concepts were compiled, which consist in highlighting the position of each expert on the main consequences of land degradation. As a result, a generalized expert model of the problem field of the social consequences of land degradation was formed. According the model all experts note the interdisciplinary nature of the study of the issues under consideration, which are placed at the intersection of environmental, economic and social problems. The overwhelming majority of experts noted the direct nature of the impact of land degradation on the formation of social consequences. Thanks to the integration of private concepts, it was possible to identify such aspects on which there are discrepancies. That provides an opportunity for a broader study of the social consequences of land degradation. However, there is an expert opinion that the social consequences are rather indirect and are realized through resource problems. Some experts draw attention to the fact that there are the extreme forms of land degradation that significantly increases the manifestation of social consequences. According to experts, land degradation can lead to a change in social status; a decrease in the recreational potential of land; hunger; a change in life expectancy, job loss; increased stratification of society; changes in the cost of housing and a change in the type of land use; reducing the use of land for agricultural needs and changing people’s attitudes to more individualistic ones. It was also noted that the use of products from degraded lands could lead to an increase in cancer incidence in the region. Conceptualization and identification of these problems could help to focus efforts in the field of studying the social problems of land degradation.

The paper considers the spatial heterogeneity of the flow of eroded soil material to the foot of the plowed slope and further to the side of the valley in the presence of a lyncahrt resulting fr om mechanical tillage on the lower border of arable land. A small catchment area in the area of intense Chernobyl pollution has been studied, wh ere the po- sition of the lower boundary of the arable land over the past few decades coincides with the upper boundary of the side of the valley. This made it possible to trace the spatial patterns of the distribution of eroded material with stable functioning of the lynchart as an important lithodynamic boundary accumulating and redistributing the slope runoff of sediments. The determination of the volume of material coming from arable slopes was carried out using mathematical modeling of erosion based on a high-precision digital terrain model, climate data, soil erodibility and crop rotations. To assess the intensity of accumulation, 137Cs of Chernobyl origin was used as a reliable tracer. The bulk of the eroded material enters the valley network through a system of slope hollows that concentrate the slope runoff and cut through the valleys. In the areas of the valleys sides outside the runoff concentration zones, the re- deposition of the material mainly depends on the morphology of the lyncahrt, occurs locally and is associated with episodic overflows as a result of the gradual filling of the depression before the lyncart. Under existing conditions, accumulation on the sides of the valley occupies a relatively small share in the total sediment balance of the studied catchment area. Significant changes may occur due to a gradual decrease in the barrier role of the soil as a result of sediment accumulation and climatic changes that contribute to an increase in erosion rates.