Galina Vladislavovna Stulina

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Salt neoformations in the soils of the Aral Sea dried bottomMoscow University Bulletin. Series 17. Soil science. 2022. 3. p.36-47Galina V. Kharitonova Evgenii V. Shein Valeria O. Krutikova Galina V. Stulina Alexander V. Dembovetskyread more560
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Salt neoformations in sandy and silty loam soils of the Aral Sea dried bottom in the south-western part were studied by X-ray fluorescence, electron microscopic, sedimentation methods of analysis and laser diffractometry. The surface layers of soils are significantly saline and enriched with CaCO3. The distribution of CaCO3 over the area is quite uniform, which indicates relatively close conditions of its formation during desiccation. The salt content varies from 0.4 to 1.2% in sands and from 3.1 to 5.8% in silty loam. The latter are characterized by the highest salinity, when, in addition to gypsum and halite, readily soluble salts are formed: eugsterite (2Na2SO4.CaSO4.2H2O), astrakhanite (Na2SO4.MgSO4.4H2O), and mirabilite (Na2SO4.10H2O). Precipitation of calcite upon drying leads to the formation of CaCO3-ooids in sands and CaCO3- microaggregates from clay and silty particle in silty loam. The reason for the increased activity of easily soluble salts in the processes of aeolian transport has been established. This transport and, correspondingly, the salinization of adjacent territories are facilitated by the blocking of adsorption centers in clays by calcite, which prevents the binding of easily soluble salts in clay-salt microaggregates.
Keywords: soil texture; salt compositions; carbonates; evaporites; electron microscopy
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