Articles

We discuss the dynamics of the snow cover and its composition for the period 2013-2018 is shown that the annual dynamics of the snow cover is characterized by the alternation of high and low values. Thus, the highest values were typical for the winter of 2012/2013, followed by a decrease in 2013/2014. The leading role in the distribution of snow cover belongs to the position of the elementary landscape within the geochemical landscape. In all years of research, the water equivalent of snow cover is characterized by bicarbonate-calcium composition. The content of micro components in General is in the same order with the results given for the South taiga landscapes. Some excess of individual components in the composition of snow water in comparison with Meshchersk and Baikal landscapes, taken as a background, due to the proximity of the studied geochemical landscape and the main road M-10 (Moscow-St. Petersburg). It is assumed that the relatively high content of calcium in the snow water of the superaqueous landscape is associated with its possible arrival from the surface of meadowmarsh carbonate soils, boiling from the surface. Sulfate ion has been found to play a leading role in the diagnosis of atmogeochemical pollution, which is partially established for the studied landscapes.

The resistance to mineralization of water soluble organic matter (WSOM) extracted from a litter of Podzol is increased upon the interaction with the mineral horizons. Both the fraction of WSOM susceptible to mineralization and the average rate of decomposition decrease after the passage through E-horizon, by 2-3 times respectively, in comparison with the values obtained for the initial WSOM. Sorption in the BF horizon gives extra stability to the incoming organic matter. The relative content of mineralized carbon is reduced to 2% (by 8 times). In natural soils sorbed organic matter can be even more resistant to the mineralization, due to lower temperatures and less biological activity, so it can be considered as the basis for the formation of a humus storage. Taking into account the calculated rate of mineralization, the accumulation of the organic carbon in the BF horizon due to WSOM sorption, may range up to 13,5/100 g per year, but this value depends on the concentration of organic substances in soil solutions, hydrological regime and other factors.

The influence of anthropogenic activity on the quality of urban alluvial soils, the conditions of growth and the state of tree plantations is estimated. The level of negative consequences for natural components correlates with the degree of human exposure. In the profile of soils moisture decreases, humus content varies in different directions, pH of waters and electrical conductivity increase. Densification of soils and inhibition of biological activity are noted in the surface horizons. The coefficient of the ecological state of soils decreases by 6-24% compared to the optimum conditions. The correlation analysis showed the presence of a significant weak matching between vegetation state and soil quality (Spearman's coefficient is -0,53).

A comparative description of the structural and functional organization of plant litter and forest floor in the course of natural postagrogenic reforestation in the chronory series of ecosystems for 12, 40 and 100 years is given. As the age of the stand increases, an increase in the total reserves and diversity of litter types, a decrease in the proportion of easily decomposable components, and a decrease in their pH and ash content are found. The change of ground cover is accompanied by the replacement of grass cover with grass-shrub, which indicates a decrease in the trophicity of ecosystems. The characteristics of the litter are adequately reflected by the composition of the ground cover. As the stand is restored, a regular decrease in the decomposition intensity of the ground detritus and the speed of the biological cycle occurs. Spatial differentiation of litter types serves as a trigger for the subsequent divergence of soil organic profiles.

Speciation of ²²⁶Ra and ²³²Th in sod-podzolic-gley concretionary soil are studied. It has been shown that with periodic overmoistening by surface waters and alternation of reducing and oxidizing conditions, the mobility and availability to plants of ²²⁶Ra is substantially higher than ²³²Th. The sum of fractions available to plants (water-soluble and exchangeable) and mobile (water-soluble, exchangeable and mobile) of ²²⁶Ra is 2-10 times higher than ²³²Th. Segregated ferruginous nodules formed in the eluvial horizons of this soil have a weak effect on the mobility of ²²⁶Ra, but significantly reduce the mobility of ²³²Th, much of which is substantially fixed inside the crystal lattices of newly formed minerals.

The ²²⁶Ra, ²³²Th, ⁴⁰K vertical profiles were studied in relation with the soil properties: pH_H2O, the sum of exchangeable Ca²⁺ and Mg²⁺, the degree of saturation with bases, the content of humus, mobile forms of phosphorus and potassium. An increase in the specific activity of ²²⁶Ra, ²³²Th, ⁴⁰K associated with the accumulation of humus and the biogenic accumulation of mobile forms of potassium and phosphorus in the upper 0-10 cm layer of horizon A in the soil of the oak forest was detected. The removal of ²²⁶Ra from the middle part of the profile of dark gray forest deep-carbonate soil was recorded. A positive correlation between the specific activity of ²²⁶Ra and the sum of the exchange bases Ca²⁺ and Mg²⁺ indicating the conjugate behavior of these elements-analogues in the horizons A, A(AE), AB and the lower horizons B1, B2, B3 was revealed. Removal of ²³²Th from horizon A(AE) and accumulation in horizon AB under conditions of local podzolization of dark gray forest soil in birch forest was observed.

The application of the express method of indirect evaluation of the mobility of heavy metals by the index of specific electrical conductivity of soil in model experiments with given parameters and homogeneity is proposed. It was established that the electrical conductivity indices obtained with a direct measurement of the electric resistance of the soil are closely correlated with the data of the instrumental method of quantitative element analysis. The maximum efficiency of the sorbent is shown in relation to cadmium, the degree of absorption reaches 61,6% with the component composition of sorbent 1:3 (sapropel to lime). For plumbum, the effective composition of the sorbent at the ratio of sapropel and lime is 1:1 - 14,3% sorbed ions, for zinc, with a ratio of the ingredients 1:5 is 6,4%.

An approach is proposed for the assessment of ecosystem services of various components of the landscape of urban forest parks. The methodology takes into account the environmental and recreational functions of the territory, is based on the interconnection of ecosystem services, ecological functions and the properties of individual components of the landscape. The assessment is carried out in a differentiated way, taking into account the decrease in the quality of the services provided in conditions of significant anthropogenic load. It is shown that the greatest contribution to the cost of services is made by the soil.

The problem of elaboration and implementation of innovative, feasible, ecologically friendly nature-like technologies aiming at an increase in carbon (C) stock and significant reduction in greenhouse gas (GG) emission from all agricultural areas, including those under rice cultivation, is critically important. In field tests conducted in Hunan Province, China, carbon dioxide (CO₂) sequestration by roots of rice plants was evaluated as influenced by silicon (Si) fertilizers. The amount of additional CO₂ sequestrated was dependent on the content of plant-available Si in agrochemicals, frequency and duration of their application and granulometric composition of soil. The data obtained evidences the potential of Si fertilizers to promote the process of C sequestration and reduction in GG emission under rice cultivation. Their application provided an increase in rice yield by 12,1 to 71,2% and in the CO₂ fixation by root system by 0,95 to 14,9 t ha^-1 over one season. Returning C to soil and fertility reproduction could be provided via enhanced plant root system development and increased root debris after harvesting. Agrochemicals containing silicon available for plants should be included in the technology for the implementation of 4R-STRATEGY of mineral nutrition of agricultural crops.

Expression of the total chemical analysis in the form of oxides has significant drawbacks: this conditional form does not correspond to the actual content of soil minerals. Oxide form distorts the view of the relationship between the different elements in the soil. It is obvious that the total chemical composition should be expressed in the form of elements including oxygen - the element with the maximal Clarke. Thus it is necessary to consider the amendment on oxygen loss on ignition of the soil. The studied soil on amendments to oxygen can be divided into three groups. For spodosols of Russian plain after amendments oxygen content increases slightly and total chemical composition of practically does not change. For vertisols of southern Siberia after amendments oxygen content increases by 3 - 4%. Not accounting for this fact leads to a noticeable error in the content of K. For oxisols in Norfolk Island with a high proportion of unstable gibbsite after amendments content O increases by 7 - 8%. This leads to a noticeable error in the contents: O, Al, Fe and Ti in particular. For oxisols the amendment of oxygen is required.